Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base

  1. Corredoira-Vázquez, Julio 1
  2. González-Barreira, Cristina 1
  3. Deibe, Ana M. García 1
  4. Sanmartín-Matalobos, Jesús 1
  5. Fondo, Matilde 1
  1. 1 Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
Actas:
The 25th International Electronic Conference on Synthetic Organic Chemistry

Ano de publicación: 2021

Tipo: Achega congreso

DOI: 10.3390/ECSOC-25-11740 GOOGLE SCHOLAR lock_openAcceso aberto editor

Resumo

This work describes an uncommon new case of imine hydrolysis, leading to the formation of a carboxylate group. The conditions of the media that favor this conversion, which seem to be mediated by the presence of DyIII, are analyzed. The process brings about the formation of a dysprosium complex of formula {[(DyL2)2Na2(H2O)8][Et3NH]2[DyL2]2}·14H2O (1). Single X-ray characterization of the final product is reported.

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