Total Hydrolysis of a New Imidazolidine Induced by ZnII

  1. Fondo, Matilde 1
  2. Doejo, Jesús 1
  3. García-Deibe, Ana 1
  4. Sanmartín-Matalobos, Jesus 1
  5. Concepción González-Bello 1
  1. 1 Universidade de Santiago de Compostela
    info
    Universidade de Santiago de Compostela

    Santiago de Compostela, España

    ROR https://ror.org/030eybx10

    Localización xeográfica da organización Universidade de Santiago de Compostela
Actas:
Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry

Ano de publicación: 2014

Tipo: Achega congreso

DOI: 10.3390/ECSOC-18-A026 GOOGLE SCHOLAR lock_openAcceso aberto editor HANDLE: https://hdl.handle.net/10347/25956
Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela: lock_openAcceso aberto Handle

Obxectivos de Desenvolvemento Sustentable

Resumo

2,2´-(2-(2-hydroxyphenyl)imidazolidin-1,3-diyl)diethanol(H3L) was obtained by condensation between 2-hydroxybenzaldehyde and N,N'-bis(2-hydroxyethyl)ethylenediamine. Its potential ability as NNOOO donor towards ZnII was tested. This study shows that zinc(II) mediates the fast hydrolysis of H3L, yielding the free aldehyde and amine. This latter was crystallographically characterised, showing a supramolecular 1D architecture based on hydrogen bond interactions.